Beat pudding mix and milk in a medium bowl with whisk for 2 minutes. Stir in 1/2 cup Cool Whip.
Slice angel food cake horizontally into three layers. Stack cake layers on a plate, spreading pudding mixture between layers.
Microwave chocolate and remaining Cool Whip in a microwaveable bowl on high for 30 seconds. Stir until chocolate is completely melted and mixture is well blended. Spoon over cake.
Refrigerate 1 hour.
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