Wash potatoes and place, unpeeled, in a large pot. Fill pot so that the water just covers the potatoes, salt the water, and bring to a boil. Reduce to a simmer and cook until the potatoes can be easily pierced with a fork, about 20 minutes or so.
Drain and place in the refrigerator to cool completely.
Cut cooled potatoes into 1" to 1 ½" chunks.
In a large bowl, whisk together mayonnaise, lemon zest and juice, chives, and dijon mustard. Add salt and pepper to taste. Add potatoes to mixture and toss to combine.